Stability and Hydrolyzation of Metal Organic Frameworks with Paddle-Wheel SBUs upon Hydration
نویسندگان
چکیده
منابع مشابه
Porous metal-organic truncated octahedron constructed from paddle-wheel squares and terthiophene links.
A metal-organic truncated octahedron (termed MOP-28) has been constructed from six rigid square-shaped Cu2(CO2)4 paddle-wheel building units and twelve 2,2':5',2' '-terthiophene-5,5' '-dicarboxylate (TTDC) linkers. TTDC linker in the cis,cis conformation provides the critical 90 degrees linkage for this unique construction. The porous structure of MOP-28 is maintained even after the removal of ...
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ژورنال
عنوان ژورنال: Chemistry of Materials
سال: 2012
ISSN: 0897-4756,1520-5002
DOI: 10.1021/cm301427w